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After speaking with each other (and sharing a beating from Yami, due to him complementing her clothes and Rito getting into a perverted mishap), he understands more about Rito's life with aliens and all the misfortunes happening around him.
He sympathizes with Rito, but remarks that at least his life is more exciting.
Yuu first noticed Rito when he saw him trying to defend Yui, and has since been interested in keeping track of his sister's relationship with Rito.
He would often mention his name at home in front of Yui just to make fun of her.
Since then, he has taken notice of Yui's relationship with Rito.
He can easily read his sister's poorly hidden feelings and her love for Rito, and is eager to see his sister become more open to romance through Rito.
After finding Rito and Yui being chased by hoodlums, he defends the two of them from the ruffians, while noticing Yui's interaction with a boy like Rito and commenting that he hopes Yui will grow to be more mature.
Akiho is someone Yuu is currently dating, but she isn't taking it as seriously as he does.
He feels disapointed everytime she turns down his invitations with some excuse.
Rito seems to like Yuu, as he finds him to be a really cool and understandable person.
He is one of several people who knows that Riko Yuusaki is in fact Rito.